Calculate adiabatic pressure, volume or gamma from any four values using P₁V₁^γ = P₂V₂^γ with absolute pressure in psi, bar, atm, kPa or Pa and volume in ft³, m³, L or US gallons. Choose the unknown in Solve for.

Reversible adiabatic ideal-gas model with a constant heat-capacity ratio. Enter absolute pressure, not gauge pressure. All pressures and volumes must be positive; γ must exceed 1.

Use a value for your gas and temperature range; no gas property is assumed.

Adiabatic Pressure Formula

The adiabatic pressure relationship used by this calculator is based on a reversible adiabatic process for an ideal gas:

P₁ V₁γ = P₂ V₂γ
  • P₁ = initial absolute pressure
  • V₁ = initial volume
  • P₂ = final absolute pressure
  • V₂ = final volume
  • γ = adiabatic index, also called the heat capacity ratio

To calculate the missing variable, the formula is rearranged as needed:

P₁ = (P₂ V₂γ) / (V₁γ)
V₁ = ((P₂ V₂γ) / (P₁))1 / γ
P₂ = (P₁ V₁γ) / (V₂γ)
V₂ = ((P₁ V₁γ) / (P₂))1 / γ
γ = (ln(P₁) - ln(P₂)) / (ln(V₂) - ln(V₁))

Choose the unknown in Solve for and enter the other four values. The calculator converts absolute pressure to Pa and volume to m³, then converts the result to your selected unit. The unitless heat-capacity ratio must be greater than one and is assumed constant through this reversible ideal-gas process.

Common Adiabatic Index Values

The value of γ depends on the gas. Use a value that matches the gas and conditions in your problem.

Gas type Typical γ Notes
Monatomic gases 1.67 Helium, argon, neon
Diatomic gases 1.40 Air, nitrogen, oxygen near room temperature
Triatomic gases 1.30 to 1.33 Carbon dioxide and similar gases, approximate
Water vapor About 1.33 Depends on temperature and pressure

Pressure and Volume Unit Reference

Quantity Supported units Base unit used internally
Pressure psi, bar, atm, kPa, Pa Pa
Volume ft³, m³, L, US gal m³
Adiabatic index Unitless Unitless

Example Calculations

Example 1: Calculate final pressure

Suppose air expands adiabatically from an initial absolute pressure of 100 psi and an initial volume of 2 ft³ to a final volume of 4 ft³. Use γ = 1.4.

P₂ = (P₁ V₁γ) / (V₂γ)
P₂ = (100 × 21.4) / (41.4)
P₂ ≈ 37.89 psi

The final pressure is about 37.89 psi.

Example 2: Calculate final volume

Suppose a gas starts at 200 kPa absolute and 10 L, then reaches 500 kPa absolute. Use γ = 1.4 and solve for final volume.

V₂ = ((P₁ V₁γ) / (P₂))1 / γ
V₂ = ((200 × 101.4) / (500))1 / 1.4
V₂ ≈ 5.20 L

The final volume is about 5.20 L.

FAQ

What does adiabatic mean?

An adiabatic process is a process where no heat is transferred into or out of the gas. For an ideal gas in a reversible adiabatic process, pressure and volume follow the relationship P₁V₁γ = P₂V₂γ.

What value should you use for γ?

Use the heat capacity ratio for the gas in your problem. For air near room temperature, γ is usually taken as 1.4. For monatomic gases such as helium or argon, γ is usually about 1.67. If your problem gives a specific value, use that value.

Why does pressure change when volume changes adiabatically?

During adiabatic compression, the gas volume decreases and the pressure rises. During adiabatic expansion, the gas volume increases and the pressure falls. Because no heat is exchanged, the change in pressure is tied to both the volume change and the gas property γ.